Comparative Magnetic Studies in the Solid State and Solution of Two Isostructural 1D Coordination Polymers Containing CoII/NiII-Curcuminoid Moieties

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Comparative Magnetic Studies in the Solid State and Solution of Two Isostructural 1D Coordination Polymers Containing CoII/NiII-Curcuminoid Moieties

Two novel 1D coordination chains containing the curcuminoid (CCMoid) ligand 9Accm have been characterized: [Co(9Accm)2(4,4 ́-bpy)]n (1) and [Ni(9Accm)2(4,4 ́-bpy)]n (2). The two compounds were synthesized by solvothermal and microwave (MW) assisted techniques, respectively, and crystals of both systems were directly obtained from the mother solutions. Crystal structures of 1 and 2 prove that both...

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Preparation of ZnO Nanocrystals with Desired Morphology from Coordination Polymers through a Solid-state Decomposition Route

One-dimensional (1D) coordination polymer, [Zn(4,4´-bpy)(H2O)4](ADC).4H2O (1) (4,4´-bpy = 4,4´-bipyridine and H2ADC = acetylenedicarboxylic acid), and three-dimensional (3D) metal-organic framework (MOF), Zn(ADC)2.(HTEA)2(2) (HTEA = triethylamine) were prepared at room temperature. The compounds were characterized by single-crystal X-ray diffraction and powder X-ray diffraction (PXRD) analyses....

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ژورنال

عنوان ژورنال: Magnetochemistry

سال: 2016

ISSN: 2312-7481

DOI: 10.3390/magnetochemistry2030029